Assessment of MgZr4P6O24 as a Solid Electrolyte for Sensing Mg in Molten Non-Ferrous Alloys
                        
                        
                            - Submitting institution
 
                            - 
                                The University of Leeds
                                
 
                            
 
                            - Unit of assessment
 
                            - 12 - Engineering
 
                            - Output identifier
 
                            - CHEM-112
 
                            - Type
 
                            - D - Journal article
 
                                - DOI
 
                                - 
                                        10.1149/1945-7111/ab6556
                                
 
                                - Title of journal
 
                                - Journal of the Electrochemical Society
 
                                - Article number
 
                                - 027532
 
                                - First page
 
                                - -
 
                                - Volume
 
                                - 167
 
                                - Issue
 
                                - 2
 
                                - ISSN
 
                                - 0013-4651
 
                                - Open access status
 
                                - Compliant
 
                            - Month of publication
 
                            - January
 
                            - Year of publication
 
                            - 2020
 
                            - URL
 
                            - 
-                            
 
                            - Supplementary information
 
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-                            
 
                            - Request cross-referral to
 
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                            - Output has been delayed by COVID-19
 
                            - No
 
                            - COVID-19 affected output statement
 
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                            - Forensic science
 
                            - No
 
                            - Criminology
 
                            - No
 
                            - Interdisciplinary
 
                            - No
 
                            - Number of additional authors
 
                            - 
                                2
                            
 
                            - Research group(s)
 
                            - 
-                            
 
                            - Proposed double-weighted
 
                            - No
 
                            - Reserve for an output with double weighting
 
                            - No
 
                            - Additional information
 
                            - Mg-ion conductors are important for developing Mg-batteries, potentiometric gas sensors and Mg-sensors for in-line process control and monitoring of alloying/casting/recycling operations in non-ferrous metallurgical industries, leading to significant cost and energy savings. Building on preliminary 2016 work describing the sol-gel synthesis of a new family of inorganic solid electrolytes which undergo solid-state phase transformation between 1173-1273K (pubs.acs.org/doi/10.1021/acs.jpcc.6b05036), this work developed and tested sensing capabilities of the material forming the basis for a successful KTP (Innovate UK-KTP008993) proposal with Rautomead Ltd to produce a sensor for measuring Mg in molten metals that integrates with the process control system during continuous casting.
 
                            - Author contribution statement
 
                            - -
 
                            - Non-English
 
                            - No
 
                            - English abstract
 
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